Mild and Efficient Iodination of Aromatic Compounds with Pyridine–Iodine Monochloride Complex (PyICI)
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چکیده
منابع مشابه
Iodination of nucleic acids in organic solvents with iodine monochloride.
Iodine monochloride, labeled with 1z51, iodinated ribonucleic acid and deoxyribonucleic acid dissolved as hexadecyltrimethylammonium salts in anhydrous dimethylformamide or N-ethyl acetamide. In the case of RNA (polyuridylate, polycytidylate, and soluble RNA) 5-iodouridine S/-phosphate, 8-iodoguanosine 5’-phosphate, and 5-iodocytidine 5’-phosphate are found. After 24 hours of reaction, 32% of U...
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A technic, efficient in use ~ of I TM, has been developed for introducing I TM into 4-mg. amounts of antibody or 3,-globulin protein at a level of 10 me. I ~al per mg. protein with a resulting iodine content of ~-S atoms per protein molecule of 160,000 molecular weight. Oak Ridge I TM was adjusted to pH 8 with borate buffer and the requisite amount of hydrochloric acid. To this solution was add...
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Efficient Oxidative Dehydrogenation of Dihydropyrimidinones and Thiocyanation of Aromatic Compounds Using 1,1,2,2-Tetrahydroperoxy-1,2-diphenylethane as the Oxidant
A new, efficient and mild approach for the oxidative dehydrogenation of dihydropyrimidinones and thiocyanation of aromatic compounds using 1,1,2,2-tetrahydroperoxy-1,2-diphenylethane (THPDPE) as a terminal oxidant was developed. Initially, various substrates bearing different electron-donating and electron-releasing functionalities were synthesized and next under the optimized reaction conditio...
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ژورنال
عنوان ژورنال: Journal of Chemical Research
سال: 1999
ISSN: 1747-5198,2047-6507
DOI: 10.1177/174751989902300102